Woodwardfieser rules for calculating absorption maximum in. Woodwardfieser rules are several sets of empirically derived rules which attempt to predict the wavelength of the absorption maximum. Estas incluyen a las reacciones electrociclicas, cicloadiciones, y reacciones sigmatropicas. Other contributions there are three sets of rules 1. All structured data from the file and property namespaces is available under the creative commons. This file is licensed under the creative commons attributionshare alike 3. Application of woodward fieser rules in structural elucidation. Azamu shahiullah department of pharmacy brac university. Other readers will always be interested in your opinion of the books youve read. It may be acyclic or 6 membered or 5 membered ring systems.
Woodwardfieser rule for conjugated dienes and polyenes. Though the woodwardhoffmann rules were first stated in terms of electrocyclic processes, they were eventually generalized to all pericyclic reactions, as the similarity and patterns in the above selection rules should indicate. Woodward fieser rules dienes the rules begin with a base value for lmax of the chromophore being. F, cl, br o i ch3ch2ch2cl 1cloropropano alquenos enlace doble carbonocarbono but1eno alquinos enlace triple. The woodwardhoffmann symbol for the ene reaction is.
When the wavelength of the transition exceeds the uv range, based on the same principle, even the. Luis pedro arana flores arana flores, luis pedro 1 u. R alquilo 10 nm cl 15 nm br 25 nm ho 35 nm ro 35 nm rco 2 6 nm sustituyentes en. This document was uploaded by user and they confirmed that they have the permission to. Una inicial, nombre o apellido mas corto o solo, precede. Assignment on woodward fieser rules advanced pharmaceutical analysis phr 410 submitted by, md. May 05, 2016 woodward fieser rules for uv spectrometry 1. We will continue our discussion on woodward fieser rules for dienes.
Woodwards rules, named after robert burns woodward and also known as woodwardfieser rules for louis fieser are several sets of. To calculate the maximum wave length of organic compounds. R alquilo 12 nm cl 12 nm br 30 nm ho 30 nm ro 30 nm jap 17. Atomic and molecular absorption spectrometry for pollution.
97 31 1159 1316 1448 987 553 133 289 1242 249 730 613 1534 392 1255 1148 1060 1303 1249 929 1141 425 50 915 1343 1161 1138 966 745